In chemistry, a lyonium ion is the cation derived by the protonation of a solvent molecule. IUPAC Gold Book - lyonium ion For example, a hydronium is formed by the protonation of water, and is the cation formed by the protonation of methanol.
Its counterpart is a lyate ion, the anion formed by the deprotonation of a solvent molecule.
Lyonium and lyate ions, resulting from molecular autoionization, contribute to the molar conductivity of protolytic solvents.
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